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Corrosion behavior of Pd48.2Fe17Co16.7Si13.4B4.7 and Pd51.4Fe18Co18Si11.1B1.5 alloys was examined by potentiodynamic polarization tests in pH 8.5 buffer solution. The amorphous alloy ribbons showed passivity with the passive current densities of 2 × 10−6 A/cm2~4 × 10−6 A/cm2. The crystalline alloys showed a higher corrosion rate in pH 8.5 buffer solution with the degree of variation depending on the alloy composition. It is suggested from the Mott-Schottky analysis that the donor density was lower for the amorphous alloy than the crystalline alloy.

Effects of Crystallization on the Corrosion and Passivity of Amorphous Pd-Fe-Co-Si-B Alloys