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Density functional theory was used to investigate structure and properties of polyvinyl alcohol complexes with halides of second group elements XHal2 (X = Be, Mg, Ca, Zn, Sr, Cd, Ba, and Hg; Hal = F, Cl, Br, and I). PVA can form hybrid interpolymeric complexes with some of them. These complexes show double spiral structure of two types

Structure of Hybrid Interpolymeric Complexes of Polyvinyl Alcohol and Halides of Second Group Elements