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Three new Zr-Cu-Ni-Al bulk metallic glasses were developed through appropriate mixing of three binary eutectics Zr38.2Cu61.8, Zr51Al49, and Zr64Ni36. By suppressing solidification of competing crystalline phases, a new glass forming alloy Zr51Cu24.22Ni14.06Al10.72 with the critical diameter of up to 10 mm is obtained.

Selection of the Composition with High Glass Forming Ability in Zr-Cu-Ni-Al Bulk Metallic Glasses