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The values of pseudo-first-order rate constants ( k   obs ) for alkaline hydrolysis of  1 , obtained at 1.0 mM NaOH and within [ C  m  E  n  T] (total concentration of C  m  E  n  ) range of 3.0–5.0 mM for C 12 E 23  and 10–20 mM for C 18 E 20 , fail to obey pseudophase micellar (PM) model. The values of the fraction of near irreversible C  m  E  n   micellar trapped  1  molecules ( F   IT1 ) vary in the range ~0–0.75 for C 12 E 23  and ~0–0.83 for C 18 E 20  under such conditions. The values of  F   IT1  become 1.0 at ≥10 mM C 12 E 23  and 50 mM C 18 E 20 . Kinetic analysis of the observed data at ≥10 mM C 12 E 23  shows near irreversible micellar entrapment of  1  molecules under such conditions.

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Kinetic Evidence for Near Irreversible Nonionic Micellar Entrapment of<i>N</i>-(2′-Methoxyphenyl)phthalimide (1) under the Typical Alkaline Reaction Conditions

Kinetic Evidence for Near Irreversible Nonionic Micellar Entrapment ofN-(2′-Methoxyphenyl)phthalimide (1) under the Typical Alkaline Reaction Conditions