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In this study, a novel method was proposed to synthesize high quality Zn-doped CuInS 2  nanocrystals under high frequency magnetic field at ambient conditions. The magnetic Zn-doping gave superparamagnetic heating of the resulting nanocrystals via magnetic induction, causing an accelerating growth rate of the doped CuInS 2  under ambient conditions faster than conventional autoclave synthesis. Shape evolution of the Zn-doped CuInS 2  nanocrystals from initially spherical to pyramidal, to cubic, and finally to a bar geometry was detected as a function of time of exposure to magnetic induction. These colloidal solvents with different shaped nanocrystals were further used as “nanoink” to fabricate a simple thin film solar device; the best efficiency we obtained of these crystals was 1.01% with a 1.012   μ  m thickness absorber layer (bar geometry). The efficiency could be promoted to 1.44% after the absorber was thickened to 2.132   μ  m.

A Novel Method for Preparation of Zn-Doped CuInS2Solar Cells and Their Photovoltaic Performance

A Novel Method for Preparation of Zn-Doped CuInS₂Solar Cells and Their Photovoltaic Performance