Synthesis and Characterization of a New N"‐[(1Z,2E)‐2‐ (Hydroxyimino)‐1‐phenylpropylidene]‐N"′‐[(1E)‐phenylmethylene]thiocarbonohydrazide and its Complexes with Co(II), Ni(II) and Cu(II)
Author(s) -
Dilip C. Sawant,
A. Venkatchallam,
R. G. Deshmukh
Publication year - 2009
Publication title -
journal of chemistry
Language(s) - English
Resource type - Journals
eISSN - 2090-9071
pISSN - 2090-9063
DOI - 10.1155/2010/525197
Subject(s) - chemistry , metal , characterization (materials science) , metal ions in aqueous solution , molar conductivity , ligand (biochemistry) , elemental analysis , solvent , crystallography , divalent , divalent metal , ion , coordination complex , conductivity , inorganic chemistry , stereochemistry , nanotechnology , organic chemistry , materials science , receptor , biochemistry
Synthesis and characterization of a new N"-[(1Z,2E)-2- (Hydroxyimino)-1-phenylpropylidene]-N"'-[(1E)-phenylmethylene]thiocarbonohydrazide and its metal complexes with Co(II), Ni(II) and Cu(II) metal ions. The ligand synthesis and characterization is reported for first time. The complexes of divalent metal ions were synthesized in 1:2 molar proportion using ethanol as solvent. The ligands as well as its metal complexes were characterized using various physicochemical techniques such as elemental analysis, spectral and magnetic measurements and electrical conductivity measurements in case of the metal complexes only. The data for the metal complexes reveals that they may be represented by ML2. The metal complexes show interesting features of coordination structure
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