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The fluorescence/phosphorescence excitation spectra, the dispersed fluorescence/phosphorescence spectraand the sensitized phosphorescence excitation spectrum have been measured for jet-cooled p-benzoquinone.The assignments of vibronic bands in the  1 B 1g (n - ,   π  ∗   ) ←  1 A g  and  1 A u (n + ,   π  ∗   ) ←  1 A g  transitionshave been definitely established. The phosphorescence spectra from vibronic levels of  3 A u  exhibit afeature of single vibronic level emission. The  3 A u  ←  1 A g  transition was also vibrationally analyzed.

laser chemistry

Singlet And Triplet n,<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:msup><mml:mi>π</mml:mi><mml:mo>∗</mml:mo></mml:msup></mml:math> Transitions of Jet-Cooled p-Benzoquinone

Singlet And Triplet n,π∗ Transitions of Jet-Cooled p-Benzoquinone