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A new family of insertion-compound electrodes, so called NCIMs  (Nano-Crystallite-Insertion-Materials),has been proposed: the major requirement is that the electrode materials have to be polycrystallinewith a crystallite and particle size as small as possible (the accepted definition being that many crystallitesmake a particle). Indeed, by minimizing the size of the crystallites, the formation of defects bonds isfavored, particularly at the.crystallite surface, acting as reversible (de)grafting sites of Li+. Also, thecation-anion bonding is weakened not only in the grain boundary region but also within the crystalliteclose to its surface: then the electrochemical insertion of Li+ takes place through easy bonding rearrangements

Mechanisms of the Reversible Electrochemical Insertion of Lithium Occurring With NCIMs (Nano-Crystallite-Insertion-Materials)