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Tin (Sn)-doped beta phase gallium oxide ( β -Ga 2 O 3 ) nanostructures at different Sn concentrations (0 to 7.3 at%) are synthesized using a facile hydrothermal method. The Sn-doped  β -Ga 2 O 3  nanostructures are characterized using scanning electron microscopy, transmission electron microscopy, energy dispersive X-ray spectroscopy, X-ray powder diffraction, X-ray photoelectron spectroscopy, and absorbance spectroscopy. In addition, their photocatalytic activity is evaluated by observing methylene blue degradation under ultraviolet light (254 nm) irradiation. The photocatalytic activity of the Sn-doped (0.7 at%)  β -Ga 2 O 3  nanostructures is significantly enhanced compared to that of intrinsic  β -Ga 2 O 3  nanostructures due to the elevated charge separation. Excessive Sn concentrations (exceeding 2.2 at%) above the solid solubility limit of the Sn in  β -Ga 2 O 3  nanostructures lead to SnO 2  and SnO precipitation. The presence of SnO 2  and SnO degrades the photocatalytic efficiency in the  β -Ga 2 O 3  nanostructures. The results suggest new opportunities for the synthesis of highly effective  β -Ga 2 O 3 -based photocatalysts for applications in environmental remediation, disinfection, and selective organic transformations.

Hydrothermal Synthesis and Photocatalytic Property of Sn-doped β-Ga2O3 Nanostructure

Hydrothermal Synthesis and Photocatalytic Property of Sn-doped β-Ga₂O₃ Nanostructure