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A carbon corrosion model is developed based on the formation of surfaceoxides on carbon and platinum of the polymer electrolyte membrane fuel cellelectrode. The model predicts the rate of carbon corrosion under potential holdand potential cycling conditions. The model includes the interaction of carbonsurface oxides with transient species like OH radicals to explain observedcarbon corrosion trends under normal PEM fuel cell operating conditions. Themodel prediction agrees qualitatively with the experimental data supporting thehypothesis that the interplay of surface oxide formation on carbon and platinumis the primary driver of carbon corrosion.

A Carbon Corrosion Model to Evaluate the Effect of Steady State and Transient Operation of a Polymer Electrolyte Membrane Fuel Cell