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Various experimental and molecular simulation methods are used to investigate water adsorption and its related effects on ion dynamics in two typical examples of microporous solids: Na + -faujasites and homoionic alkali exchanged montmorillonites. Influence of the confinement, of the cationic density and of the cation size is examined. It is then shown that all these parameters play a key role in water adsorption thermodynamics and in the cation/water subsystem dynamics.

Effect of Water Adsorption on Ion Dynamics in Confined Geometry: Na+-Faujasites and Homoionic Alkali Exchanged Montmorillonite

Effect of Water Adsorption on Ion Dynamics in Confined Geometry: Na⁺-Faujasites and Homoionic Alkali Exchanged Montmorillonite