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Hard X-ray and extremely low energy bulk-sensitive photoelectron spectroscopyhas been performed in the temperature range of 100-330 K for Fe3O4. In the hightemperature phase just above the Verwey transition, the intensity at the Fermilevel (EF) is still negligible, but it increases gradually with furtherincreasing the temperature (250 K, 330 K) in consistence with the temperaturedependence of the conductivity. The spectral behaviors near EF with temperatureare well explained by the model, which takes the polaron effect into account.

Polaronic Behavior of Photoelectron Spectra of Fe3O4 Revealed by Both Hard X-ray and Extremely Low Energy Photons

Polaronic Behavior of Photoelectron Spectra of Fe₃O₄ Revealed by Both Hard X-ray and Extremely Low Energy Photons