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We report on the fragmentation dynamics of triply charged, diatomic,molecular ions of NO and CO. Dissociative fragmentation after multipleionization of NO and CO is studied under the impact of 200 keV proton beamusing recoil-ion momentum spectrometer. Kinetic Energy Release distributions(KERDs) for various fragmentation channels were obtained. We have alsocalculated the potential energy curves (PECs) for ground and several excitedstates of NO^{3+} and CO^{3+} molecular ion. The obtained KERDs are discussedin the background of the calculated PECs as well as the simple Coulombexcitation model. Coulomb breakup of the unstable precursor molecular ion showsa clear preference for the N^{2+} + O^+ (and C^{2+} + O^+) fragmentationchannel.

the european physical journal. d, atomic, molecular and optical physics/the european physical journal. d, atomic, molecular, optical and plasma physics

Fragmentation dynamics of diatomic molecules under proton impact: Kinetic energy release spectra of CO^{q+} and NO^{q+} (q = 2, 3) molecular ions