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A new scheme of state classification is proposed and applied to analyzemasses of the heavy baryons $\Omega_{Q}$, $\Sigma_{Q}$ and $\Xi_{Q}^{\prime}$in P-waves. The results confirm all excited $\Omega_{c}$ and $\Omega_{b}$baryons reported recently by LHCb to be bound states of a P-wave $ss$-diquarkand a respective charm or bottom quark, and thereby predict Regge trajectoriesfor more excited $\Omega_{c}$ and $\Omega_{b}$ baryons. We suggest one excited{$J^{P}=5/2^{-}$} $\Omega_{b}$ state to be unseen by LHCb around $6352$ MeV,and predict P-wave masses of all spin-partners of the odd-parity baryons$\Sigma_{c}(2800)/\Xi_{c}^{\prime}(2942)$ and$\Sigma_{b}(6097)$/$\Xi_{b}^{\prime }(6227)$. A computation is further given ina relativized potential quark models to explain matched values of spincouplings of all considered baryons, by which a scaling law for these spincouplings is discussed.

A Mixing Coupling Scheme for Spectra of Singly Heavy Baryons with Spin-1 Diquarks in P-waves