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We report the synthesis and mesophase characterization of a series of novel hexaalkoxydibenzanthracenes to probe the effect of side-chain length variation and substituents on the mesophase temperature range. A series of hexaalkoxydibenz[a,c]anthracenes (2a–2i) with varying chain lengths were prepared by Suzuki coupling of the appropriate boronate ester with the corresponding dialkoxydibromonaphthalenes, followed by oxidative cyclization. Compounds 2a–2i were also brominated in the 10 and 13 positions to yield the corresponding dibromo series, 4a–4i. While none of the compounds, 2a–2i, exhibited columnar mesophases, all of the compounds in series 4a–4i did exhibit columnar phases over broad temperature ranges. To further investigate the effect of substituents on the mesomorphic properties of hexaalkoxydibenzanthracenes, we also prepared iodo-substituted 8, nitro-substituted 9, and amino-substituted 10. A comparison of the mesophase temperature range with previously reported compounds 3–7 shows that electro...

Probing the structural features that influence the mesomorphic properties of substituted dibenz[a,c]anthracenes