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An unusual reaction between 1,3-dithiane anions and by 5-(alkylsulfanyl)-1-phenyltetrazoles has been discovered in which the dithiane anion formally displaces the 1-phenyltetrazole ring from sulfur to provide a sulfanylated dithiane.

Sulfanylation of 1,3-dithiane anions by 5-(alkylsulfanyl)-1-phenyltetrazoles