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An iterative method for calculating the polar component of the solvationGibbs energy under a smooth change in dielectric permittivity, both between asubstrate and a solvent and in a solvent is formulated on the basis of apreviously developed model. The method is developed in the approximation of thelocal relationship D = \eps (r) E between the displacement vectors D and theelectric field intensity E.

russian journal of physical chemistry. b

Continuous dielectric permittivity II: An Iterative Method for  Calculating the Polar Component of the Molecular Solvation Gibbs Energy Under  a Smooth Change in the Dielectric Permittivity of a Solution