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First result of experiment for searching of 2K-capture of Xe-124 with thelarge-volume copper proportional counter is given. The 12 litre sample with63.3% (44 g) of Xe-124 was used in measurements. The limit on the half-life ofXe-124 with regard to 2K(2\nu)-capture for the ground state of Te-124 has beenfound: T_{1/2} > 4.67x10^{20} y (90% C.L.). A sample with volume 52 Lcomprising of Xe-124 (10.6 L - 58.6 g) and Xe-126 (14.1 L - 79.3 g) will usedat the next step of the experiment to increase a sensitivity of 2K-caption ofXe-124 registration. In this case sensitivity to the investigated process willbe at the level of S=1.46 x 10^{21} y (90% C.L.) for 1 year measurement.

First result of the experimental search for the 2K-capture of Xe-124 with the copper proportional counter