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This review deals with heterogeneous hydroformylation catalysts, specificallymetal complexes fixed in an organic polymer structure. It describes the maincatalyst synthesis methods, provides data on hydroformylation of unsaturatedcompounds (including asymmetric hydroformylation), and shows how those compoundscan be used. The special focus is on the systematization of data onheterogeneous catalysts developed on the basis of porous organic polymers. Dueto their porous structure, resistance to organic media and the highconcentration of heteroatoms they contain, these materials can be consideredpromising for developing highly active, selective and stable heterogeneouscatalysts for hydroformylation of unsaturated compounds, particularly higherlinear olefins.

Polymeric Heterogeneous Catalysts in the Hydroformylation of Unsaturated Compounds