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Paleozoic blueschist facies rocks are relatively scarce on Earth due to warmer geother- mal gradients at that time and/or later reequilibration. Ferro-magnesiocarpholite (Fe-Mg carpholite), the typical low-temperature blueschist facies index mineral in metapelites, was discovered 30 yr ago and is known only in Tethyan belts metamorphosed ,80 m.y. ago. Herein we report the discovery of Paleozoic Fe-Mg carpholite in the ca. 470 Ma blueschists of Motalafjella, Svalbard Caledonides, the oldest known occurrence on Earth. The car- pholite-bearing rocks reached pressure-temperature (P-T) conditions of 15-16 kbar and 380-400 8C and followed a nearly isothermal exhumation path. In the cooling Earth per- spective, these P-T estimates for Motalafjella blueschists demonstrate the existence of cold subduction-zone gradients (;7 8C/km) from the middle Paleozoic onward.

Discovery of Paleozoic Fe-Mg carpholite in Motalafjella, Svalbard Caledonides: A milestone for subduction-zone gradients