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A bacterial strain, designated KSM-7358, that can use α-cedrene for growth was isolated. The strain was identified as a member of the genusRhodococcus and catalyzed the novel allylic oxidation of α-cedrene regiospecifically to produce (R )-10-hydroxycedrene (sec -cedrenol) with a very high yield. α-Curcumene was also produced as a possible metabolite ofsec -cedrenol. A possible pathway for the microbial conversion of α-cedrene tosec -cedrenol and α-curcumene is proposed.

Novel Allylic Oxidation of α-Cedrene to sec -Cedrenol by a Rhodococcus Strain