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In this paper, we have studied the effect of short branches on the thermal conductivity of a polyethylene (PE) chain. With a reverse non-equilibrium molecular dynamics method applied, thermal conductivities of the pristine PE chain and the PE-ethyl chain are simulated and compared. It shows that the branch has a positive effect to decrease the thermal conductivity of a PE chain. The thermal conductivity of the PE-ethyl chain decreases with the number density increase of the ethyl branches, until the density becomes larger than about 8 ethyl per 200 segments, where the thermal conductivity saturates to be only about 40% that of a pristine PE chain. Because of different weights, different types of branching chains will cause a different decrease of thermal conductivities, and a heavy branch will leads to a lower thermal conductivity than a light one. This study is expected to provide some fundamental guidance to obtain a polymer with a quite low thermal conductivity.

Decreased Thermal Conductivity of Polyethylene Chain Influenced by Short Chain Branching