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In this paper, we experimentally demonstrate that molecules with maximum absorption wavelength corresponding to the first excitation energy of base liquid molecules are able to significantly improve the electrical performances of natural ester oils. The positive lightning impulse breakdown and acceleration characteristics, ac breakdown characteristics, and streamer structure of the natural ester oils, as well as the electronic properties of the molecules, are presented. The molecules with different absorptions in ultraviolet lights were doped into the natural ester oil. The positive lightning impulse breakdown characteristics of natural ester oil with different doped molecules indicated that the doped molecule with great absorption in the medium wavelength ultraviolet irradiation was able to significantly enhance the positive lightning impulse breakdown and acceleration voltages of natural ester oil by 15% and 60%, respectively. In addition, it also enhanced the ac breakdown voltage by 17%. The base liquid molecules exhibited first excitation energy of 4 eV, which corresponds to the maximum absorption wavelength of such molecules, indicating that the improved electric breakdown strength was a result of the reduced the number of excited molecules and weakened ionization of molecules during the streamer propagation.

Significantly Improved Electrical Breakdown Strength of Natural Ester Liquid Dielectrics by Doping Ultraviolet Absorbing Molecules