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The title Dy III  complex, [Dy 2 (C 7 H 6 NO 2 ) 4 Cl 2 (C 12 H 8 N 2 ) 2 ] or [Dy 2 ( μ 3 -PAA) 4 (Cl) 2 (phen) 2 ] (PAA = 3-pyridylacetate, phen = 1,10-phenanthroline), obtained by reaction of Dy(ClO 4 ) 3 , 3-pyridylacetic acid ligands and 1,10-phenanthroline, exhibits a dinuclear structure. Adjacent binuclear dimers are further connected  via  face-to-face  π – π  stacking interactions resulting in supramolecular chains along the  c -axis direction.

iucrdata

Bis[μ3-2-(pyridin-3-yl)acetato-κ3 O:O:O′]bis[μ2-2-(pyridin-3-yl)acetato-κ2 O:O′]bis[chlorido(1,10-phenanthroline-κ2 N,N′)dysprosium(III)]