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The title compound, [RuCl 2 (C 10 H 14 )(C 21 H 21 O 3 P)], crystallizes with two complex molecules in the asymmetric unit. The Ru II  atom has a classical three-legged piano-stool environment being coordinated by a cymene ligand [Ru—centroid = 1.707 (2)/1.704 (2) Å], a tris(4-methoxyphenyl)phosphane ligand [Ru—P = 2.3629 (15)/2.3665 (15) Å] and two chloride atoms with the Ru—Cl bonds adopting two distinct values of 2.4068 (16)/2.4167 (16) and 2.4016 (15)/2.4244 (16) Å. The effective cone and solid angles for the phosphane ligands were calculated to be 149.5/150.2° and 25.3/25.6°, respectively. In the crystal, weak C—H...Cl/O/π interactions are observed. The crystal was refined as a two-component twin.

Dichlorido(η6-p-cymene)[tris(4-methoxyphenyl)phosphane]ruthenium(II)

Dichlorido(η⁶-p-cymene)[tris(4-methoxyphenyl)phosphane]ruthenium(II)