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In the centrosymmetric title complex, [Cu 2 Cl 2 (C 15 H 11 N 3 ) 2 ](CF 3 O 3 S) 2 , the Cu II  metal center is fivefold coordinated by two chloride ions and three nitrogen atoms of the terpyridine ligand in a distorted square-pyramidal geometry; two trifluoromethanesulfonate ions complete the outer coordination sphere.  π–π  stacking interactions between the pyridyl rings in adjacent molecules contribute to the alignment of the complexes in columns along the  a -axis. This structure represents the first example of a binuclear dication of formula [Cu(terpy) 2 Cl 2 ] 2+  with trifluoromethanesulfonate as counter-ions.

Di-μ-chlorido-bis[(2,2′:6′,2′′-terpyridine-κ3 N,N′,N′′)copper(II)] bis(trifluoromethanesulfonate)

Di-μ-chlorido-bis[(2,2′:6′,2′′-terpyridine-κ³ N,N′,N′′)copper(II)] bis(trifluoromethanesulfonate)