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The solvated title salt, (C 8 H 15 N 2 )[NiBr 3 (P(C 6 H 5 ) 3 )]·0.5C 4 H 10 O, was obtained in the form of single crystals directly from the reaction mixture. The molecular structure consists of separated 1-butyl-3-methylimidazolium cations, tribromido(triphenylphosphane)nickelate(II) anions and half a solvent molecule of 1-butanol, all connected  via  multiple hydrogen contacts to form a three-dimensional network. The co-crystallized 1-butanol molecule is disordered and adopts two orientations. The central C—C bonds of both orientations are located on an inversion centre (Wyckoff site 2 b  of space group  P 2 1 / n ). Thereby, each orientation has again two orientations with the OH group being located either on one or the other side of the C 4  alkyl chain. The dried solvent-free compound exhibits a relatively low melting point (m.p. = 412 K).

1-Butyl-3-methylimidazolium tribromido(triphenylphosphane-κP)nickelate(II) butan-1-ol hemisolvate