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In the title compound, [CdNi(C 9 H 8 N 2 ) 2 (CN) 4 ] n , the Cd and Ni atoms both lie on centres of inversion in space group  P 2 1 / c . The Cd atom is coordinated by two bidentate quinolin-8-amine ligands and by the N atoms of two cyano ligands, while the square planar Ni atom is coordinated by the C atoms of four cyano ligands. These units form a one-dimensional coordination polymer containing an (–NC—Ni—CN—Cd–) n backbone, and the coordination polymer chains are linked into a three-dimensional array by a combination of N—H...N and C—H...N hydrogen bonds, augmented by a π–π stacking interaction.

iucrdata

catena-Poly[[bis(quinolin-8-amine-κ2 N,N′)cadmium(II)]-μ-cyanido-κ2 N:C-[dicyanidonickel(II)]-μ-cyanido-κ2 C:N]