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The title compound, [Ru(C 5 H 6 N 2 )(C 10 H 8 N 2 )(C 15 H 11 N 3 )](PF 6 ) 2  solvent, crystallizes in the triclinic space group  P \overline{1} with one dicationic Ru complex, two PF 6 −  anions, and undefined solvent in the asymmetric unit. The cation and anions are linked  via  N—H...F hydrogen bonding. One PF 6 −  anion is disordered over two positions, with occupancies 0.634 (8) and 0.366 (8). The solvent, which is located in channels in the crystal, is highly disordered. Reflection contributions from the solvent were added to the calculated structure factors using the  SQUEEZE  routine [Spek (2015)  Acta Cryst.  C 71 , 9–18] of the program  PLATON , which determined there to be 59 electrons in 264 Å 3  treated this way per unit cell. Because the exact identity and amount of solvent were unknown, no solvent was included in the atom list or molecular formula.

iucrdata

(4-Aminopyridine-κN 1)(2,2′-bipyridine-κ2 N,N′)(2,2′:6′,2′′-terpyridine-κ3 N,N′,N′′)ruthenium(II) bis(hexafluoridophosphate) unknown solvate