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The synthesis and characterization of poly[dichloridotri(1,3-thiazolidine-2-thione)cadmium(II)], [CdCl 2 (C 3 H 5 NS 2 ) 3 ] n , prepared from CdCl 2 ·H 2 O and C 3 H 5 NS 2  (tzdSH) in a 1:3 ratio, are described. The Cd II  cation is coordinated by three 1,3-thiazolidine-2-thione molecules and three Cl −  anions in a distorted octahedral environment. The Cd metal centres are connected  via  Cl −  ligands, creating polymeric chains running along the  a- axis direction. The conformation of the chains is stabilized by N—H...Cl hydrogen bonds.

catena-Poly[[chloridotris(1,3-thiazolidine-2-thione-κS)cadmium(II)]-μ-chlorido]