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The title compound, [Bi(C 9 H 6 NS 2 ) 3 ], was prepared by reacting BiCl 3  and 2-mercapto-4-phenylthiazole ( L H) at room temperature in a stoichiometric ratio of 1:4. The molecular structure reveals a slightly distorted square-pyramidal environment around the Bi III  atom. Two of the three monoanionic ligands  L −  coordinate in an  N , S -bidentate mode, while one shows a monodentate mode through an S atom. There are no significant intermolecular interactions present in the crystal.

iucrdata

Bis(4-phenyl-2-sulfanylidene-2,3-dihydro-1,3-thiazol-3-ido-κ2 S 2,N)(4-phenyl-1,3-thiazole-2-thiolato-κS 2)bismuth