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In the title complex, [NiCl 2 (C 12 H 9 N 3 ) 2 ]·H 2 O, a divalent nickel atom is coordinated by two 2-(pyridin-2-yl)-1 H -benzimidazole ligands in a slightly distorted octahedral environment defined by four N donors of two  N , N ′-chelating ligands, along with two  cis -oriented anionic chloride donors. The title complex crystallized with a water molecule disordered over two positions. In the crystal, a combination of O—H...Cl, O—H.·O and N—H...Cl hydrogen bonds, together with C—H...O, C—H...Cl and C—H...π interactions, links the complex molecules and the water molecules to form a supramolecular three-dimensional framework. The title complex is isostructural with the cobalt(II) dichloride complex reported previously [Das  et al.  (2011).  Org. Biomol. Chem .  9 , 7097–7107].

Dichloridobis[2-(pyridin-2-yl-κN)-1H-benzimidazole-κN 3]nickel(II) monohydrate

Dichloridobis[2-(pyridin-2-yl-κN)-1H-benzimidazole-κN ³]nickel(II) monohydrate