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The title compound, [Co(C 18 H 37 N 2 ) 2 (NCS) 4 ], consists of a cobalt(II) ion positioned on the origin of the triclinic unit cell. It is coordinated by the N atoms of two  trans- oriented 1-dodecyl-4-aza-1-azoniabicyclo[2.2.2]octane (DABCO + ) cations, which carry  n -dodecyl chains at the non-coordinating N atoms. The distorted octahedral coordination environment of the Co II  ion is completed through four N atoms of isothiocyanate ions, which are arranged within the equatorial plane. Non-classical hydrogen bonding of the types C—H...N and C—H...S between the filamentous molecules lead to the formation of layers parallel to (001).

Bis(1-dodecyl-4-aza-1-azoniabicyclo[2.2.2]octane)tetraisothiocyanatocobalt(II)