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In the mononuclear title complex, [Co(C 10 H 6 NO 4 ) 2 (C 7 H 10 N 2 ) 2 (H 2 O) 2 ], the Co II  ion is located on an inversion centre and has a distorted octahedral coordination geometry of type CoN 2 O 4  by two N atoms from the two 4-(dimethylamino)pyridine (DMAP) ligands, two carboxylate O atoms from the two deprotonated  N -phthaloylglycine (Nphgly) ligands [systematic name: 2-(1,3-dioxo-2,3-dihydro-1 H -isoindol-2-yl)acetate] and two coordination water molecules. In the crystal, O—H...O, C—H...O hydrogen bonds and π–π stacking interactions link the molecules into the supramolecular structure.

iucrdata

Diaquabis[4-(dimethylamino)pyridine-κN 1]bis[2-(1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl)acetato-κO 1]cobalt(II)