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The title complex, [MnBr 0.50 Cl 0.50 (C 19 H 15 N 4 O)(CO) 3 ]Br 0.49 Cl 0.51 ·CH 3 OH, exhibits substitutional disorder of the halogen ligand in the asymmetric unit, with almost the same occupancies for Br and Cl. The Mn I  atom is coordinated in a distorted octahedral environment by three carbonyl C atoms, the disordered  X −  ligand ( X  = Br or Cl) and two N atoms from the 1,10-phenanthroline ligand bearing a nicotinamide pendant moiety. The cation displays a  fac  configuration of the carbonyl ligands. There is another disorder between the chloride ligand and its  trans -situated carbonyl ligand, and between Cl −  and Br −  at the position of the counter-anion. In the crystal, intermolecular C—H... X , N—H... X , O—H... X  ( X  = Br or Cl) and C—H...O hydrogen bonds lead to the formation of a three-dimensional network.

iucrdata

fac-Bromido/chlorido(0.50/0.50)[3-carbamoyl-1-(1,10-phenanthrolin-2-ylmethyl)pyridinium-κ2 N,N′]tricarbonylmanganese(I) 0.49-bromide 0.51-chloride methanol monosolvate