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The organic molecule in the title hydrate, C 12 H 13 NO 3 S·H 2 O, is folded across the S...N vector. Chains two molecules thick extending along the  a -axis direction are formed by N—H...O and O—H...O hydrogen bonds. These interactions are reinforced by C—H...S hydrogen bonds and offset π-stacking interactions between centrosymmetrically related benzene rings. The chains are associated through C—H...O hydrogen bonds.

Ethyl 3-methyl-1-oxo-4H-1,4-benzothiazine-2-carboxylate monohydrate