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The title complex, [Mo(C 24 H 30 N 2 P 2 )(CO) 4 ], contains a molybdenum centre bearing a  P , P ′- cis -chelating Ph 2 PN( i Pr)P(Ph)NH( i Pr) and four carbonyl ligands in a distorted octahedral coordination geometry. This results in a nearly planar four-membered metallacycle. In the crystal, molecules are linked by N—H...O and C—H...O hydrogen bonds to form layers parallel to the  ac  plane. For the final refinement, the contributions of disordered solvent molecules were removed from the diffraction data with SQUEEZE in  PLATON  [Spek (2015).  Acta Cryst.  C 71 , 9–18]. The given chemical formula and other crystal data do not take into account the unknown solvent molecule( s ).

iucrdata

Tetracarbonyl[N-(diphenylphosphanyl-κP)-N,N′-diisopropyl-P-phenylphosphorus diamide-κP]molybdenum(0) with an unknown solvent