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The title compound, [AuCo2Fe2(C5H5)4(C13H11N3)2](PF6)1.2(CF3SO3)1.8, was synthesized by deprotonation of 4-cobaltoceniumyl-1-ferrocenyl-3-methyl-1,2,3-triazolium hexa­fluorido­phosphate tri­fluoro­methane­sulfonate with thallium ethoxide, followed by transmetalation with chlorido­(tri­phenyl­phosphine)gold(I), crystallizing as orange prisms. It is a unique example of a homoleptic dimetallocenyl-substituted triazolyl­idene complex.

Bis(4-cobaltoceniumyl-1-ferrocenyl-3-methyl-1,2,3-triazolylidene)gold(I) hexafluoridophosphate–trifluoromethanesulfonate (1.2/1.8)