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In the title coordination polymer, [Zn2(C6H10N3)3(NO3)]n, two independent ZnII ions are tetrahedrally coordinated by the anionic ligands, viz. 2-[(dimethylamino)methyl]imidazolate or nitrate ions. One ZnII ion is coordinated by the imidazolate N atoms of three anions and an O atom of the nitrate ion. The second ZnII ion is coordinated by imidazolate N atoms of three anions and one amino N atom of one such ligand. The 2-[(dimethylamino)methyl]imidazolate anions are bridging the ZnII ions to form a helical chain structure along [001]. The chains are further linked by the bridging ligands into a three-dimensional framework structure.  The nitrate anion is disordered over two sets of sites and was refined with two pairs of three O atoms using half-occupancy for each O atom

iucrdata

Poly[tris{μ-2-[(dimethylamino)methyl]imidazolato-κ3 N 1,N 2:N 3}(nitrato-κO)dizinc(II)]