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The title polymeric compound, {[Na2(C4H4O4)(H3BO3)(H2O)4]·H3BO3}n, comprises [101] chains of edge-sharing [NaO6] octahedra flanked by succinate and boric acid ligands. An intricate three-dimensional network is formed by O—H...O hydrogen bonds involving all components of the crystal. The crystal investigated was a non-merohedral twin; major component = 83%

catena-Poly[[sodium-di-μ-aqua-μ-(boric acid)-μ-succinato-sodium-di-μ-aqua] boric acid monosolvate]