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In the compound, [η2(N,N)-Ph2Si(NDipp)2Ge(μ-S)]2·CH3CN (Dipp = 2,6-iPr2C6H3), C72H88Ge2N4S2Si2·CH2CN, the dimeric germanethione complex lies about an inversion centre with the two GeIV atoms bridged by two sulfide ligands forming the central Ge2S2 ring. Each GeIV atom is also coordinated by two N atoms from the bulky bis(amido)silane ligands in a slightly distorted tetrahedral coordination geometry. An acetonitrile solvent molecule, disordered about an inversion centre, is also present

iucrdata

1,3,7,9-Tetrakis[2,6-bis(1-methylethyl)phenyl]-2,2,8,8-tetraphenyl-5,10-dithia-1,3,7,9-tetraaza-2,8-disila-4,6-digermadispiro[3.1.3.1]decane acetonitrile monosolvate