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The title compound, C21H19BrFN5O.0.5H2O, crystallizes as a hemihydrate with the water molecule located on a twofold rotation axis. The piperidine ring has a chair conformation, whereas the triazole and the benzisoxazole rings are planar (r.m.s. deviations = 0.006 and 0.009 A, respectively). The N-C and C-C bonds connecting the triazole and benzisoxazole rings, respectively, to the piperidine ring lie in equatorial positions. In the crystal, molecules related by a twofold rotation axis are linked via O-H...N hydrogen bonds involving the water molecule and a pair of C-H...N hydrogen bonds forming dimers. The dimers are linked via a pair of C-H...F hydrogen bonds leading to the formation of chains propagating along [101]

3-(1-{[1-(4-Bromophenyl)-1H-1,2,3-triazol-4-yl]methyl}piperidin-4-yl)-6-fluoro-1,2-benzoxazole hemihydrate