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Reaction of Zn(ClO 4 ) 2 ·6H 2 O with cyclam (cyclam = 1,4,8,11-tetraazacyclotetradecane, C 10 H 24 N 4 ) and Na 3 SbS 4  in an acetonitrile/water mixture led to the formation of crystals of the title compound, [Zn 3 (SbS 4 )(C 10 H 24 N 4 ) 3 ](SbS 4 )·2CH 3 CN·2H 2 O or [(Zn-cyclam) 3 (SbS 4 ) 2 ](H 2 O) 2 (acetonitrile) 2 . The set-up of the crystal structure is similar to that of [(Zn-cyclam) 3 (SbS 4 ) 2 ] . 8H 2 O reported recently [Danker  et al.  (2021).  Dalton Trans .  50 , 18107–18117]. The crystal structure of the title compound consists of three crystallographically independent Zn II  cations (each disordered around centers of inversion), three centrosymmetric cyclam ligands, one SbS 4 3–  anion, one water and one acetonitrile molecule occupying general positions. The acetonitrile molecule is equally disordered over two sets of sites. Each Zn 2+  cation is bound to four nitrogen atoms of a cyclam ligand and one sulfur atom of the SbS 4 3–  anion within a distorted square-pyramidal coordination. The cation disorder of the [Zn(cyclam)] 2+  complexes is discussed in detail and is also observed in other compounds, where identical ligands are located above and below the [Zn(cyclam)] 2+  plane. In the title compound, the building units are arranged in layers parallel to the  bc  plane forming pores in which the acetonitrile solvate molecules are located. Intermolecular C—H...S hydrogen bonding links these units to the SbS 4 3–  anions. Between the layers, additional water solvate molecules are present that act as acceptor and donor groups for intermolecular N—H...O and O—H...S hydrogen bonding.

acta crystallographica. section e, crystallographic communications

Crystal structure of μ<sub>3</sub>-tetrathioantimonato-tris[(cyclam)zinc(II)] tetrathioantimonate acetonitrile disolvate dihydrate showing Zn disorder over the cyclam ring planes (cyclam = 1,4,8,11-tetraazacyclotetradecane)

Crystal structure of μ3-tetrathioantimonato-tris[(cyclam)zinc(II)] tetrathioantimonate acetonitrile disolvate dihydrate showing Zn disorder over the cyclam ring planes (cyclam = 1,4,8,11-tetraazacyclotetradecane)

Crystal structure of μ₃-tetrathioantimonato-tris[(cyclam)zinc(II)] tetrathioantimonate acetonitrile disolvate dihydrate showing Zn disorder over the cyclam ring planes (cyclam = 1,4,8,11-tetraazacyclotetradecane)