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The asymmetric unit of the polymeric title compound {[Co 2 (C 12 H 7 NO 8 )(H 2 O) 2 ]·1.6H 2 O}  n  comprises two Co II ions, which are coordinated by fully deprotonated 2-aminodi-acetic terephthalic acid (adtp 4- ) and terminal water mol-ecules in distorted octa-hedral N 1 O 5 and O 6 coordination environments. The title compound features tetra-nuclear Co II units bridged by κ  3  O : O : O '- and κ  3  O : O , O '-carboxyl-ate groups, which are joined into ribbons via syn-anti carboxyl-ate bridges. The parallel adtp 4- ligands with an alternately reversed arrangement further link adjacent Co II ribbons into (010) layers, which are assembled into a three-dimensional supra-molecular network via inter-molecular hydrogen bonds. The disordered water solvent mol-ecules are situated in channels parallel to [100]. Magnetic measurements and analyses reveal that the title compound displays anti-ferromagnetic behaviour. The purity of the title compound was characterized by X-ray powder diffraction.

acta crystallographica. section e, crystallographic communications

Synthesis, crystal structure and magnetic properties of poly[[diaqua{μ<sub>6</sub>-2-[bis(carboxylatomethyl)amino]terephthalato}dicobalt(II)] 1.6-hydrate]

Synthesis, crystal structure and magnetic properties of poly[[diaqua{μ6-2-[bis(carboxylatomethyl)amino]terephthalato}dicobalt(II)] 1.6-hydrate]

Synthesis, crystal structure and magnetic properties of poly[[diaqua{μ₆-2-[bis(carboxylatomethyl)amino]terephthalato}dicobalt(II)] 1.6-hydrate]