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The asymmetric unit of the title organic-inorganic hybrid complex [systematic name: ethane-1,2-diaminium hexa-chlorido-stannate(IV)-4-meth-oxy-benz-alde-hyde (1/2)], (C 2 H 10 N 2 )[SnCl 6 ]·2C 8 H 8 O 2 , contains one half of an ethyl-enedi-ammonium cation, one half of an [SnCl 6 ] 2- anion and one p -anisaldehyde mol-ecule. Both the organic cation and the quasi-regular octa-hedral inorganic anion are located about inversion centres. The organic cations and [SnCl 6 ] 2- anions lie in layers parallel to the ac plane with p -anisaldehyde mol-ecules occupying the space between the layers. A network of classical N-H⋯Cl and N-H⋯O hydrogen bonds exists between the ethyl-enedi-ammonium cations and the [SnCl 6 ] 2- anions and p -anisaldehyde mol-ecules. These inter-actions, together with non-classical C-H⋯O inter-actions between the ethyl-enedi-ammonium cations and the p -anisaldehyde mol-ecules, serve to hold the structure together. The crystal studied was refined as a two-component twin.

A new organic–inorganic compound, ethylenediammonium hexachloridostannate(IV) p-anisaldehyde disolvate