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The triazene derivative, ( E )-1,3-dimethyl-2-[(4-nitro­phen­yl)triaz-2-enyl­idene]-2,3-di­hydro-1 H -imidazole was synthesized by coupling 1,3-di­methyl­imidazolium iodide with 1-azido-4-nitro benzene. The title compound has monoclinic ( C 2/ c ) symmetry and an  E  conformation about the –N= N– bond.

Crystal structure and spectroscopic properties of (E)-1,3-dimethyl-2-[3-(4-nitrophenyl)triaz-2-enylidene]-2,3-dihydro-1H-imidazole