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The crystal structures are reported of the 6,6-di-fluoro-6 H -dibenzo[ c , e ][1,2]oxaborinin-6-ide (or 9,9-di-fluoro-10-oxa-9-boraphenanthren-9-ide) anion with two different cations, namely, potassium 6,6-di-fluoro-6 H -dibenzo[ c , e ][1,2]oxaborinin-6-ide, K + ·C 12 H 8 BF 2 O - , ( II ), featuring a polymeric structure, and bis-(tetra-phenyl-phospho-nium) bis-(6,6-di-fluoro-6 H -dibenzo[ c , e ][1,2]oxaborinin-6-ide) aceto-nitrile tris-olvate, 2C 24 H 20 P + ·2C 12 H 8 BF 2 O - ·3CH 3 CN, ( III ), which is composed of discrete cations, anions and aceto-nitrile solvent mol-ecules linked by C-H⋯O, C-H⋯N and C-H⋯F hydrogen bonds. There are only minor differences in the geometrical parameters of the anions in these structures.

Two salts of the 6,6-difluoro-6H-dibenzo[c,e][1,2]oxaborinin-6-ide anion with different cations