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In the title compound, {[Au(C 26 H 24 P 2 S 2 )][AuBr 2 ]}  n  , the gold(I) centres of the cation are coordinated by the P=S groups of the di-sulfide ligands to form a chain polymer parallel to the c axis. Both independent gold atoms lie on the same twofold axis, and the midpoint of the H 2 C-CH 2 bond lies on an inversion centre. The anions flank the polymeric chain; they are connected to it by short aurophilic inter-actions and C-H⋯Br contacts, and to each other by Br⋯Br contacts.

acta crystallographica. section e, crystallographic communications

Crystal structure of the unusual coordination polymer catena-poly[[gold(I)-μ-1,2-bis(diphenylphosphinothioyl)ethane-κ2 S:S′] dibromidoaurate(I)]