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In the title salt, di-μ-oxido-bis-{2,6-bis-[(di-methyl-amino)-meth-yl]phenyl-κ C  1 }tellurium(-IV) bis[tri-chlorido-(dimethyl sulfoxide-κ S )platinate(II)], (C 24 H 38 N 4 O 2 Te 2 )[PdCl 3 (C 2 H 6 OS)] 2 , which crystallizes in the triclinic space group P , each Te atom is in a distorted five-coordinated TeO 2 N 2 C square-pyramidal geometry (τ values of 0.026 and 0.001) with the C atoms of the phenyl rings occupying the apical positions. The phenyl rings in the [C 24 H 38 N 4 O 2 Te 2 ] 2+ cation are in a cis arrangement to enable this species to participate in Te⋯Cl cation-anion inter-actions. There are also C-H⋯O inter-actions involving the dimethyl sulfoxide ligands and numerous cation-anion and anion-anion C-H⋯Cl inter-actions, which link the ions into a complex three-dimensional array.

acta crystallographica. section e, crystallographic communications

Structure of a diorganotelluroxonium(IV) cation, {[2,6-(CH2NMe2)2C6H3Te(μ-O)]2}2+, with the trichlorido(dimethyl sulfoxide)platinum(II) anion