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The title compound, [FePt(C 19 H 18 OS 2 )(C 18 H 15 P)(C 25 H 22 P 2 )(CO) 2 ], 1 , [(OC) 2 Fe(μ-dppm)(μ-C(=O)C(CH 2 SC 6 H 4 Me-4)=CCH 2 SC 6 H 4 Me-4)Pt(PPh 3 )], represents the first example of a diphosphane-bridged heterobimetallic Fe-Pt dimetalla-cyclo-pentenone complex resulting from a bimetallic activation of metal-coordinated carbonyl ligand with an inter-nal alkyne, namely 1,4-bis-( p -tolyl-thio)-but-2-yne. The bridging μ 2 -C(=O)C(CH 2 SC 6 H 4 Me-4)=CCH 2 SC 6 H 4 Me-4 unit (stemming from a carbon-carbon coupling reaction between CO and the triple bond of the alkyne di-thio-ether) forms a five-membered dimetalla-cyclo-pentenone ring, in which the C=C bond is π-coordinated to the Fe center. The latter is connected to the Pt center through a short metal-metal bond of 2.5697 (6) Å.

acta crystallographica. section e, crystallographic communications

Crystal structure of {μ2-1,2-bis[(4-methylphenylsulfanyl]-3-oxoprop-1-ene-1,3-diyl-1:2κ2C3:C1}dicarbonyl-1κ2C-[μ2-methylenebis(diphenylphosphane)-1:2κ2P:P′](triphenylphosphane-2κP)ironplatinum(Fe—Pt), [(OC)2Fe(μ-dppm){μ-C(=O)C(4-MeC6H4SCH2)=CCH2SC6H4Me-4}Pt(PPh3)]